『壹』 如何製取Cu的納米顆粒 至少兩種方法 多多益善
以一氧化碳，氧氣，水為原料直接法制過氧化氫的新型納米金屬銅催化劑及其制備方法。現有技術中直接法合成過氧化氫催化劑活性組分多採用貴金屬，且存在過氧化氫時空產率偏低等不足。本發明催化劑由銅、金屬修飾劑及載體材料組成。各組分的重量配比為：銅含量在5-20wt％之間，金屬修飾劑在1-5wt％之間，其餘組分為載體材料。所述銅主要以尺寸在5-20nm之間的金屬納米顆粒形式高度分散在載體上，該催化劑是通過化學還原法還原含有Cu2+離子及金屬修飾劑的載體，然後去除雜質離子後製得。應用於以一氧化碳，氧氣，水為原料的直接法合成過氧化氫反應時，該種催化劑具有比以往專利報道的貴金屬Pd催化劑更為優良的過氧化氫時空產率，具有良好的工業應用前景。
『貳』 催化劑研究方面比較好的導師
Catalysis Research of Relevance to Carbon Management: Progress, Challenges, and Opportunities
Hironori Arakawa, Michele Aresta,....Tobin J. Marks
Chem. Rev. 2001, 101, 953-996此篇作者基本匯集了世界上一半的著名催化科學家，必讀！
Organic Reactions at Well-Defined Oxide Surfaces
Mark A. Barteau特拉華大學的催化牛人
Chem. Rev. 1996, 96, 1413-1430
ACID-BASE REACTIONS ON SOLID SURFACES: THE REACTIONS OF HCOOH, H&O, AND HCOOCH3 WITH OXYGEN ON Ag (110)
M.A. BARTEAU, M. BOWKER and R.J. MADIX三位牛人的固體表面酸鹼反應
Surface Science 94 (1980) 303-322
Chemical Structures and Performance of Perovskite Oxides
M. A. Pen and J. L. G. Fierro關於鈣鈦礦氧化物的牛人綜述
Chem. Rev. 2001, 101, 1981-2017
The Binary Rare Earth Oxides二元稀土氧化物
Gin-ya Adachi* and Nobuhito Imanaka
Chem. Rev. 1998, 98, 1479-1514
Oxygen vacancies in transition metal and rare earth oxides: Current state of understanding and remaining challenges過渡金屬和稀土氧化物的氧空穴，很著名的綜述
M. Veronica Ganglia-Pirovano, Alexander Hofmann, Joachim Sauer
Surface Science Reports 62 (2007) 219–270 **的一句名言「中東有石油，中國有稀土。」
Classical kinetics of catalytic reactions
Gérald Djéga-Mariadassou and Michel Boudart
Journal of Catalysis 216 (2003) 89–97經典的機理與催化反應，必讀！
Role of the Crystal-Field Theory in Determining the Structures of Spinels
Jeremy K. Burdett 伯德特金屬固體物理
J. Am. Chem. Soc. 1982, 104, 92-95
Hideshi Hattori服部英教授的多相鹼催化3篇綜述，填補田部教授的固體酸催化
Heterogeneous Basic Catalysis多相鹼催化唯一Chem Rev綜述
Chem. Rev. 1995, 95. 537-550
CATALYSIS BY BASIC METAL OXIDES金屬氧化物的鹼性催化
Materials Chemistry and Physics, 18 (1988) 533-552
Solid base catalysts: generation of basic sites and application to organic synthesis
Applied Catalysis A: General 222 (2001) 247–259固體鹼催化劑
Solid base catalysts for the synthesis of fine chemicals
Yoshio Ono
Journal of Catalysis 216 (2003) 406–415 前面講過Robert J. Davis的一篇在J Catal上的分子篩鹼催化綜述
「Intelligent」 reforming catalysts: Trace noble metal-doped Ni/Mg(Al)O derived from hydrotalcites
Katsuomi Takehira 必將風靡的智能重整催化劑
Journal of Natural Gas Chemistry 18(2009) 237–259
SURFACE RECONSTRUCTION AND CATALYSIS
G. A. Somorjai
Annu. Rev. Phys. Chern. 1994.45: 721-51表面重建與催化
High technology catalysts towards 100% selectivity Fabrication, characterization and reaction studies
G.A. Somorjai*, R.M. Rioux
Catalysis Today 100 (2005) 201–215高選擇性的研究
POTENTIAL ENERGY SURFACES FOR CHEMICAL REACTIONS AT SOLID SURFACES
Barbara J. Garrison and Deepak Srivastava在固體表面化學反應的勢能面
Annu. Rev. Phys. Chern. 1995.46: 373-94
Elementary Processes at Gas/Metal Interfaces
By Gerhard Ertl
Angew Chem IE (1976)金屬界面
Monitoring in situ catalytically active states of Ru catalysts for different methanol oxidation pathways
R. Blume…R. Schlogl…and M. Kiskinova*弗里茨哈珀所的釕基催化
Phys. Chem. Chem. Phys., 2007, 9, 3648–3657
Mechanism of HCl oxidation (Deacon process) over RuO2
Núria López...Javier Pérez-Ramírez 牛人JPR教授在制氯的綜述
Journal of Catalysis 255 (2008) 29–39
Substitutional alloy of Ce and Al
Qiao-Shi Zeng…鈰鋁結晶石，浙大去年很有影響力的一篇
PNAS February 24, 2009 vol. 106 no. 8 2515–2518
Deactivation of metal catalysts in liquid phase organic reactions
Michèle Besson, Pierre Gallezot 液相有機反應中金屬催化劑的失活
Catalysis Today 81 (2003) 547
Process options for converting renewable feedstocks to bioprocts
Pierre Gallezot 可再生的原料
Green Chem., 2007, 9, 295–302
Catalytic Conversion of Biomass: Challenges and Issues
Pierre Gallezot 生物質催化轉化
ChemSusChem 2008, 1, 734 – 737
New possibilities and opportunities for basic and applied research on selective oxidation by solid catalysts: an overview
G. Centia,*, M. Misonob 固體催化劑的選擇性氧化綜述
Catalysis Today 41 (1998) 287
The Desorption of Alcohols from Metal Oxides.
D. J. WHEELER…醇在金屬氧化物表面的脫附
J Catal, 1960
Research Perspectives ring 40 Years of the Journal of Catalysis
Frank S. Stone 催化學報40年歷史的總結
Journal of Catalysis 216 (2003) 2–11
Environmental catalysis
François Garin 環境催化綜述
Catalysis Today 89 (2004) 255–268
Catalytic conversion of methane to more useful chemicals and fuels: a challenge for the 21st century
Jack H. Lunsford 甲烷的催化轉化展望
Catalysis Today 63 (2000) 165–174
Natural gas chemical transformations: The path to refining in the future
Eardo Falabell, Sousa-Aguiar…天然氣的未來
Catalysis Today 101 (2005) 3–7
Characterization of zeolite basicity using probe molecules by means of infrared and solid state NMR spectroscopies固體核磁表徵分子篩的鹼性
Manuel Sanchez-Sanchez, Teresa Blasco *
Catalysis Today 143 (2009) 293–301
Transition metal phosphide hydroprocessing catalysts: A review
S. Ted Oyama…加氫催化綜述
Catalysis Today 143 (2009) 94–107
Concepts in Theoretical Heterogeneous Catalytic Reactivity
Rutger A. Van Santen; Matthew Neurock大牛的多相催化轉化的理論概念
Catalysis Reviews, 37: 4, 557
Hydrotalcite-like anionic clays in catalytic organic reactions
Bert F. Sels; Dirk E. De Vos; Pierre A. Jacobs
Catalysis Reviews, 43: 4, 443 水滑石類陰離子粘土的有機催化
Methane Oxyforming for Synthesis Gas Proction
Andrew P. E. York; Tian-cun Xiao; Malcolm L. H. Green…
Catalysis Reviews, 49:4, 511 – 560 牛津甲烷的利用
Precious Metal Catalysts Supported on Ceramic and Metal Monolithic Structures for the Hydrogen Economy
Robert J. Farrauto…氫能領域的負載型貴金屬催化劑
Catalysis Reviews, 49:2, 141 - 196
Catalytic Proction of Liquid Fuels from Biomass-Derived Oxygenated Hydrocarbons: Catalytic Coupling at Multiple Length Scales 生物質能
Dante A. Simonetti; James A. Dumesic
Catalysis Reviews, 51: 3, 441
Gas Conversion to Liquid Fuels and Chemicals: The Methanol Route-Catalysis and Processes Development
Touhami Mokrani; Mike Scurrell 甲醇經濟，氣轉液
Catalysis Reviews, 51: 1, 1
Recent Advances in the Liquid-Phase Synthesis of Metal Nanostructures with Controlled Shape and Size for Catalysis 液相中形貌尺寸可控合成納米金屬
Natalia Semagina; Lioubov Kiwi-Minsker
Catalysis Reviews, 51: 2, 147
Selective Catalysis of Lactic Acid to Proce Commodity Chemicals
Yongxian Fan; Chunhui Zhou; Xiaohong Zhu 浙工大去年很著名的乳酸催化轉化綜述
Catalysis Reviews, 51: 3, 293
Water Gas Shift Catalysis
Chandra Ratnasamy; Jon P. Wagner 水汽轉換反應
Catalysis Reviews, 51: 3, 325
Aromatic Hydrogenation Catalysis: A Review
Antonymuthu Stanislaus; Barry H. Cooper 芳烴的加氫催化
Catalysis Reviews, 36: 1, 75
Enhanced ethanol proction inside carbon-nanotube reactors containing catalytic particles
XIULIAN PAN…AND XINHE BAO* 包院士的碳納米管催化綜述
nature materials
石墨烯的化學研究進展
傅強, 包信和 科學通報2009 年第 54 卷第 18 期: 2657 ~ 2666
Chem Rev上關於多相催化著名的一期專刊
Special Issue of 『『Introction: Heterogeneous Catalysis』』
Volume 95, Number 3 May 1995
Methods for Preparation of Catalytic Materials 催化材料的制備，必讀！
James A. Schwarz, Cristian Contescu and Adriana Contescu
Oscillatory Kinetics in Heterogeneous Catalysis
Ronald lmbihl and Gerhard Ertl*
Turnover Rates in Heterogeneous Catalysis 最近被狂頂的TOF綜述，殊不知該期篇篇經典
M. Boudart
Supported Metal Clusters: Synthesis, Structure, and Catalysis 牛人的催化材料綜述
B. C. Gates
Spillover in Heterogeneous Catalysis 多相催化的溢流
W. Curtis Conner, Jr., J and John L. Falconer
Modeling the Kinetics of Heterogeneous Catalysis 模擬和機理
H. Chuan Kang*, W. H. Weinberg*
推薦幾期其他雜志多相催化相關的專刊：
Special Issue of 『『IB metals』』 Copper, Silver and Gold in Catalysis
Catalysis Today 36 (1997)
Special Issue of 『『Recent advances in catalytic proction of hydrogen from renewable sources』』
Catalysis Today 129 (2007) 263–264
Special Issue of 『『Chemistry and physics of metal oxide nanostructures』』
Phys. Chem. Chem. Phys., 2009, 11, 3607
Special Issue of 『『Catalytic Synthesis and Utilization of Alcohols』』
Catalysis Today 147 (2009) 61
德國馬普-哈伯研究所的Hans-Joachim Freund教授，有實力N/S但據說號稱絕不發表N/S的牛人
Surface chemistry of carbon dioxide 最早拜讀Freund教授的文章
Surface Science Reports 25 (1996) 225-273
Molecular beam experiments on model catalysts
Surface Science Reports 57 (2005) 157–298
Photochemistry on Metal Nanoparticles
Chem. Rev. 2006, 106, 4301-4320
Gold Supported on Thin Oxide Films: From Single Atoms to Nanoparticles
Vol. 41, No. 8 August 2008 949-956 ACCOUNTS OF CHEMICAL RESEARCH
Oxide ultra-thin films on metals: new materials for the design of supported metal catalysts
Chem. Soc. Rev., 2008, 37, 2224–2242
美國德州A&M大學化學系的D. Wayne Goodman教授，表面化學及催化牛人
Model Catalytic Studies over Metal Single Crystals
Acc. Chem. Res. 1984, 17, 194-200
Catalysis: New Perspectives from Surface Science 科學的展望
SCIENCE, VOL. 236
Model Studies in Catalysis Using Surface Science Probes 又是那一期著名的文章之一
Chem. Rev. 1995, 95, 523-536
Metal Oxide Surfaces and Their Interactions with Aqueous Solutions and Microbial Organisms
Chem. Rev. 1999, 99, 77-174
High-pressure catalytic reactions over single-crystal metal surfaces 表面催化必讀經典
Surface Science Reports 14 (1991) 1-107
Chemical and Electronic Properties of Bimetallic Surfaces 雙金屬表面
Acc. Chem. Res., Vol. 28, No. 12, 1995
Catalytically Active Gold: From Nanoparticles to Ultrathin Films
Acc. Chem. Res. 2006, 39, 739-746 Precious little catalyst 前面介紹過的NATURE, 2008
UCR的Francisco Zaera教授
Infrared and molecular beam studies of chemical reactions on solid surfaces
International Reviews in Physical Chemistry, 21: 3, 433
Regio-, Stereo-, and Enantioselectivity in Hydrocarbon Conversion on Metal Surfaces
Acc. Chem. Res. 1152-1160 August 2009 Vol. 42, No. 8 碳水化合物
Kinetics of Chemical Reactions on Solid Surfaces: Deviations from Conventional Theory
Acc. Chem. Res. 2002, 35, 129-136 固體表面的催化
Organic chemistry on solid surfaces馬博士的文章
Surface Science Reports 61 (2006) 229–281
瑞士蘇黎世聯邦理工的Alfons Baiker教授
Aerogels in Catalysis
Catalysis Reviews, 37: 4, 515 — 556
Supercritical Fluids in Heterogeneous Catalysis
Chem. Rev. 1999, 99, 453-473
Utilization of carbon dioxide in heterogeneous catalytic synthesis²
Appl. Organometal. Chem. 14, 751–762 (2000)
Heterogeneous Enantioselective Hydrogenation over Cinchona Alkaloid Modified Platinum: Mechanistic Insights into a Complex Reaction
Acc. Chem. Res. 2004, 37, 909-917
Oxidation of Alcohols with Molecular Oxygen on Solid Catalysts
Chem. Rev. 2004, 104, 3037-3058
Catalytic Oxidations in Dense Carbon Dioxide
Chem. Rev. 2009, 109, 2409–2454 拜科教授的綜述值得一讀
NOx Storage-Rection Catalysis: From Mechanism and Materials Properties to Storage-Rection Performance
Chem. Rev. 2009, 109, 4054–4091
『叄』 納米二氧化硅光催化劑合成技術的研究現狀與進展
去納米或者科學網等查查唄~~
『肆』 貴金屬催化劑發展前景
催化劑來按來源來分，可分為生自物催化劑和非生物催化劑。非生物催化劑目前大多數是工業催化劑，它們都是由人工合成的，是具有特定組成和結構的製品。
工業催化劑按材質分，可分為金屬催化劑、金屬氧化物催化劑、硫化物催化劑、酸鹼催化劑和絡合催化劑等；按使用領域來分，工業催化劑又可分為煉油催化劑、化工催化劑和環保催化劑等。
前瞻網發布的《2014-2018年 中國催化劑行業深度調研與投資戰略規劃分析報告》隨著能源供需矛盾的日趨嚴峻，能源產品價格的大幅波動，能源結構的多元化以及環境污染的日趨惡化，我國政府和行業主管部門對石油、煤炭、天然氣等能源生產過程及產品的凈化十分重視，出台了許多有利於行業發展的產業政策與措施。
『伍』 金屬納米催化劑的發展狀況
催化劑按來源來分，可分為生物催化劑和非生物催化劑。非生物催化劑目前大多數是工業催化劑，它們都是由人工合成的，是具有特定組成和結構的製品。
工業催化劑按材質分，可分為金屬催化劑、金屬氧化物催化劑、硫化物催化劑、酸鹼催化劑和絡合催化劑等；按使用領域來分，工業催化劑又可分為煉油催化劑、化工催化劑和環保催化劑等。
前瞻網發布的《2014-2018年 中國催化劑行業深度調研與投資戰略規劃分析報告》隨著能源供需矛盾的日趨嚴峻，能源產品價格的大幅波動，能源結構的多元化以及環境污染的日趨惡化，我國政府和行業主管部門對石油、煤炭、天然氣等能源生產過程及產品的凈化十分重視，出台了許多有利於行業發展的產業政策與措施。
（1）根據《產業結構調整指導目錄》規定，催化劑產品涉及煤炭氣化、液化及多聯產技術開發、煤炭高效洗選脫硫及污染物綜合控制與利用技術開發及應用、油氣田提高採收率技術、安全生產保障技術、生態環境恢復與污染防治工程技術開發利用以及含硫含酸重質、劣質原油以及高硫重油、高硫石油焦綜合利用等有關能源開采清潔生產等領域，屬於國家鼓勵發展的行業。
（2）根據《當前優先發展的高技術產業化重點領域指南》（2007年）規定，本行業產品涉及其第75子類的油品加氫技術及設備、加氫裂化催化劑和相關技術、劣質原油和渣油加氫技術、催化裂化原料預加氫技術、煤液化油加氫提質技術、費-托合成油加氫改質技術、特種油品的加氫技術、催化裂化等二次加工技術、油品精製技術、潤滑油加氫技術和生產超清潔汽柴油的油品加氫技術，屬於國家優先發展的高技術產業。
（3）2009年5月國務院出台的《石化產業調整和振興規劃》和《煤炭產業政策》，提出了扶持骨幹企業、重點企業的產品種類，以及扶持高端替代產品的種類，提出了推動企業技術改造，開展煉油企業油品質量升級改擴建等。同時對環境與生態保護也提出了更加嚴格的要求，對於本行業的發展也構成有力的政策支持。